TDPAC and beta-NMR applications in chemistry and biochemistry
Time differential perturbed angular correlation (TDPAC) of.-rays spectroscopy has been applied in chemistry and biochemistry for decades. Herein we aim to present a comprehensive review of chemical and biochemical applications of TDPAC spectroscopy conducted at ISOLDE over the past 15 years, includi...
Elmentve itt :
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| Dokumentumtípus: | Cikk |
| Megjelent: |
2017
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| Sorozat: | JOURNAL OF PHYSICS G-NUCLEAR AND PARTICLE PHYSICS
44 No. 6 |
| doi: | 10.1088/1361-6471/aa666b |
| mtmt: | 3265998 |
| Online Access: | http://publicatio.bibl.u-szeged.hu/16372 |
| Tartalmi kivonat: | Time differential perturbed angular correlation (TDPAC) of.-rays spectroscopy has been applied in chemistry and biochemistry for decades. Herein we aim to present a comprehensive review of chemical and biochemical applications of TDPAC spectroscopy conducted at ISOLDE over the past 15 years, including elucidation of metal site structure and dynamics in proteins and model systems. beta-NMR spectroscopy is well established in nuclear physics, solid state physics, and materials science, but only a limited number of applications in chemistry have appeared. Current endeavors at ISOLDE advancing applications of beta-NMR towards chemistry and biochemistry are presented, including the first experiment on Mg-31(2+) in an ionic liquid solution. Both techniques require the production of radioisotopes combined with advanced spectroscopic instrumentation present at ISOLDE. |
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| ISSN: | 0954-3899 |