Metastable wetting model of electrospun mats with wrinkled fibers

Electrospun mats with targeted wettability are a way forward to diversify their mainstream applications and can facilitate in creating a platform for a remarkable set of properties. Limited control over the fiber morphology and surface chemistry, along with the complex architecture of electrospun ma...

Teljes leírás

Elmentve itt :
Bibliográfiai részletek
Szerzők: Amit Rawal
Siddharth Shukla
Sumit Sharma
Danvendra Singh
Yi-Min Lin
Vásárhelyi Lívia
Kozma Gábor
Janovák László
Dokumentumtípus: Cikk
Megjelent: 2021
Sorozat:APPLIED SURFACE SCIENCE 551
Tárgyszavak:
doi:10.1016/j.apsusc.2021.149147

mtmt:31841814
Online Access:http://publicatio.bibl.u-szeged.hu/23485
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100 1 |a Amit Rawal 
245 1 0 |a Metastable wetting model of electrospun mats with wrinkled fibers  |h [elektronikus dokumentum] /  |c  Amit Rawal 
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490 0 |a APPLIED SURFACE SCIENCE  |v 551 
520 3 |a Electrospun mats with targeted wettability are a way forward to diversify their mainstream applications and can facilitate in creating a platform for a remarkable set of properties. Limited control over the fiber morphology and surface chemistry, along with the complex architecture of electrospun mats, pose some of the key challenges for maneuvering the wettability. Herein, we present the design principles that underpin the key determinants responsible for a metastable state of a water droplet on electrospun mats possessing wrinkled surface topography. A 'first-of-its-kind' analytical model of apparent contact angle based on the modified Cassie-Baxter state has been proposed that accounts for the dual-scale roughness originating from fiber wrinkles and protuberances created by fiber-fiber contacts. Three-dimensional (3D) fiber and structural parameters obtained via X-ray microcomputed tomography (microCT) analysis served as key inputs for predictive modeling. The analytical model of the apparent advancing and receding contact angles has been validated with electrospun mats having well-defined orientation characteristics. In general, the theory and experiments are in reasonable agreement. Although similar magnitudes of static and advancing contact angles of water on surfaces of randomly and aligned electrospun mats have been experimentally observed, the receding contact angles differed significantly. 
650 4 |a Fizikai tudományok 
650 4 |a Kémiai tudományok 
650 4 |a Anyagmérnökség 
700 0 1 |a Siddharth Shukla  |e aut 
700 0 1 |a Sumit Sharma  |e aut 
700 0 1 |a Danvendra Singh  |e aut 
700 0 2 |a Yi-Min Lin  |e aut 
700 0 2 |a Vásárhelyi Lívia  |e aut 
700 0 2 |a Kozma Gábor  |e aut 
700 0 2 |a Janovák László  |e aut 
856 4 0 |u http://publicatio.bibl.u-szeged.hu/23485/1/Metastablewettingmodelofelectrospunmatswithwrinkledfibers.pdf  |z Dokumentum-elérés