Effect of different swelling agents on textural and structural properties of modified mesoporous silica

In this study was carried out the preparation of some large-pore ordered mesoporous silicas using a proper surfactant with different swelling agents. In order to use a micelle swelling agent with a moderate swelling ability we selected three swelling agents: 1-phenyldecane, butyl benzene and mesityl...

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Elmentve itt :
Bibliográfiai részletek
Szerzők: Popa Alexandru
Borcanescu Silvana
Barvinschi Paul
Bajuk-Bogdanović Danica
Uskoković-Marković Snežana
Holclajtner-Antunović Ivanka
Testületi szerző: International Symposium on Analytical and Environmental Problems (25.) (2019) (Szeged)
Dokumentumtípus: Könyv része
Megjelent: 2019
Sorozat:Proceedings of the International Symposium on Analytical and Environmental Problems
Kulcsszavak:Kémia
Online Access:http://acta.bibl.u-szeged.hu/64832
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520 3 |a In this study was carried out the preparation of some large-pore ordered mesoporous silicas using a proper surfactant with different swelling agents. In order to use a micelle swelling agent with a moderate swelling ability we selected three swelling agents: 1-phenyldecane, butyl benzene and mesitylene. The aim of these synthesis was to achieve a pore diameter enlargement but in the same time to avoid the formation of heterogeneous and/or poorly defined nanostructure of silica. These composites were characterized by FT-IR spectroscopy, X-ray diffraction at low angles, nitrogen physisorption at 77 K, SEM-EDS. In the view of a possible use of these amino-functionalized mesoporous silicas as adsorbents for CO2 removal, their adsorption– desorption properties towards CO2 were investigated by the TPD method. CO2 adsorption isotherms of amino-functionalized mesoporous silicas measured at 50, 60 and 70 °C showed that the adsorption capacity (mg CO2/g adsorbent) depend on the temperature of adsorption and on the type of swelling agents and amination reagents used. 
695 |a Kémia 
700 0 1 |a Borcanescu Silvana  |e aut 
700 0 1 |a Barvinschi Paul  |e aut 
700 0 2 |a Bajuk-Bogdanović Danica  |e aut 
700 0 2 |a Uskoković-Marković Snežana  |e aut 
700 0 2 |a Holclajtner-Antunović Ivanka  |e aut 
710 |a International Symposium on Analytical and Environmental Problems (25.) (2019) (Szeged) 
856 4 0 |u http://acta.bibl.u-szeged.hu/64832/1/proceedings_of_isaep_2019_226-230.pdf  |z Dokumentum-elérés