Új Cu-komplexek Schiff-bázisokkal és fizikai-kémiai vizsgálatuk
In our research we synthesized novel [Cu(4-benzyl-2-hydroxy-propiophenone)2A], [Cu(ninhydrin)2A] (A = ethylene-diamine, 1,2-, 1,3-propylene-diamine, o-phenylene-diamine) type complexes by reacting copper-acetate with different Schiff-bases in the corresponding solvent. The Schiff-bases were obtained...
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Main Authors: | |
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Corporate Author: | |
Format: | Book part |
Published: |
2016
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Series: | Proceedings of the International Symposium on Analytical and Environmental Problems
22 |
Kulcsszavak: | Elektrokémia |
Online Access: | http://acta.bibl.u-szeged.hu/56026 |
Summary: | In our research we synthesized novel [Cu(4-benzyl-2-hydroxy-propiophenone)2A], [Cu(ninhydrin)2A] (A = ethylene-diamine, 1,2-, 1,3-propylene-diamine, o-phenylene-diamine) type complexes by reacting copper-acetate with different Schiff-bases in the corresponding solvent. The Schiff-bases were obtained with the condensation of 4-benzyl-2-hydroxypropiophenone,respectively ninhydrin with diamines. We analyzed their physicochemical properties using mass spectrometry, infrared-, NMR-, UV–VIS-, ESR-spectroscopy, powderXRD and thermal analysis (TG, DTG and DTA). The copper(II)-complexes are used as antimicrobial agents. The copper(II)-complexes with aminoacids-, peptides-, chinoxaline-, mono- and bis-semicarbazones ligands are used in cancer therapy. The copper is an essential microelement in the human body. It has a very important role in the convalescence processes. The objective of the authors is to study the biological activity of the prepared complexes. |
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Physical Description: | 22-25 |
ISBN: | 978-963-306-507-5 |